[(CS(CH3)s)CoOb(I'-NO)(I'-O), a binuclear complex containing a nitrosyl bridge without a metal-metal bond
نویسندگان
چکیده
249 The compounds (CS(CH3h)Co(NO)X (X = CI, Br, I) have been prepared by reaction of [(CS(CH3)s)Coh(p.-NOh with the appropriate dihalogen X 2• Either by spontaneous decomposition or by addition of half an equivalent of [(CS(CH3)s)CoClh(p.-Clh, the chloro derivative forms the binuclear complex [(CS(CH3)s)CoClh(p.-NO)(p.-CI), the crystal structure of which indicates the presence of a nitrosyl bridge without a metal-metal bond.
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